I actually presented at .conf last year about how our 4.3 standalone indexers to 6.x clustered migration went like this:
Install the new 6.x cluster with all existing (at least those that we wanted to keep) indexes configured
Take a downtime of both the old indexers and the 6.x cluster during which you'll:
Roll hot buckets to warm on the old cluster (temporarily disabling /blocking forwarding may be necessary here)
Copy old indexes to new indexers (If you're going from 1 to multiple indexers, you can spread out the indexes across the new cluster
Ensure that the 6.x cluster has all of the existing index/parse time configurations distributed to the slave indexers
Configure the old indexers to indexAndForward to the new indexers (ensure that the 6.x receiving ports are open)
Bring back up the 6.x cluster followed by the old server(s)
What you've essentially done here is copied the data so your fresh install is now an upgrade, and made it so that any data that comes into the old cluster is also replicated over to the new cluster. This enables a controlled migration of any forwarders that you might have (especially if other teams control said forwarders) to switch over from one to the other, and all of your users data is in both places, and they can compare how dashboards and reports look in old and new environments. Now note you do double index for any new data coming into the old indexers in this scenario (at least until you retire those indexes on the old indexer, or the entire old indexers), so work with your sales rep to let them know that you're doing this. But in this way all of the data retires out as normal (still non-replicated, just like the upgrade, but all new buckets will be replicated, even in the same indexes).
If you have too much data to copy, then take sk314's suggestion (and Raghav2384's confirmation) of keeping the old indexers around as additional search peers until data retires also works, especially if you keep the same names of indexes across both of these options. However your timeline of when you want to reclaim the old hardware versus your retention time may also sway you one way or another.
You are also correct, if you went the route of putting buckets in thawed then you would have to manually remove them when you no longer want them.
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