You probably want to use a sub search that pulls the user id and matches (or NOT) across the other file. To do this:
Create a field extraction for the userid in Log A & B. The field name should be exactly the same in both extractions.
Search for all users that logged into System A and output only the userids. Similar to:
source=Log_A user_logged_in | fields userid
Use the latter search as the subsearch to find log ins for Log B. You must make sure the a field extraction exists for userid in Log B, otherwise the values passed from the subsearch won't match anything. Similar to:
source=Log_B [search source=Log_A user_logged_in | fields userid]
So, the above search should find all users that logged in to System A & B. To find users that have not logged into both, you should be able to NOT the sub search.
source=Log_B NOT [search source=Log_A user_logged_in | fields userid]
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